View from the Mars Hand Lens Imager camera on the arm of NASA’s Curiosity Mars Rover and Curiosity Self-Portrait at Mojave Site on Mount Sharp, Mars, 2015
A team using the Sample Analysis at Mars (SAM) instrument suite aboard NASA’s Curiosity rover has made the first detection of nitrogen on the surface of Mars from release during heating of Martian sediments. The nitrogen was detected in the form of nitric oxide, and could be released from the breakdown of nitrates during heating. Nitrates are a class of molecules that contain nitrogen in a form that can be used by living organisms. The discovery adds to the evidence that ancient Mars was habitable for life.
Nitrogen is essential for all known forms of life, since it is used in the building blocks of larger molecules like DNA and RNA, which encode the genetic instructions for life, and proteins, which are used to build structures like hair and nails, and to speed up or regulate chemical reactions.
However, on Earth and Mars, atmospheric nitrogen is locked up as nitrogen gas (N2) – two atoms of nitrogen bound together so strongly that they do not react easily with other molecules. The nitrogen atoms have to be separated or “fixed” so they can participate in the chemical reactions needed for life. On Earth, certain organisms are capable of fixing atmospheric nitrogen and this process is critical for metabolic activity. However, smaller amounts of nitrogen are also fixed by energetic events like lightning strikes.
Features resembling dry riverbeds and the discovery of minerals that only form in the presence of liquid water suggest that Mars was more hospitable in the remote past. The Curiosity team has found evidence that other ingredients needed for life, such as liquid water and organic matter, were present on Mars at the Curiosity site in Gale Crater billions of years ago.
“Finding a biochemically accessible form of nitrogen is more support for the ancient Martian environment at Gale Crater being habitable,” said Jennifer Stern of NASA’s Goddard Space Flight Center in Greenbelt, Maryland. Stern is lead author of a paper on this research published online in the Proceedings of the National Academy of Science March 23.
“Scientists have long thought that nitrates would be produced on Mars from the energy released in meteorite impacts, and the amounts we found agree well with estimates from this process,” said Stern.
The team found evidence for nitrates in scooped samples of windblown sand and dust at the “Rocknest” site, and in samples drilled from mudstone at the “John Klein” and “Cumberland” drill sites in Yellowknife Bay. Since the Rocknest sample is a combination of dust blown in from distant regions on Mars and more locally sourced materials, the nitrates are likely to be widespread across Mars, according to Stern.